Ruđer Bošković Institute Research Data Repository
| Title (english) | Experimental data for "Supramolecular bidentate rhodium(i) or iridium(i) phosphine and oxazoline amino acid bioconjugates as selective catalysts for enantioselective reactions" |
| Author | Zoran Kokan Ruđer Bošković Institute |
| Collaborator | Marija Bakija (Researcher) |
| Scientific / art field, discipline and subdiscipline | NATURAL SCIENCES Chemistry Applied Chemistry |
| Abstract (english) | The experimental data for the research paper Bakija et al. "Supramolecular bidentate rhodium(i) or iridium(i) phosphine and oxazoline amino acid bioconjugates as selective catalysts for enantioselective reactions", Dalton Trans., 2025, Advance Article |
| Methods (english) | The original research data are given in their original format (which can be viewed by free downloadable software) or ASCI files for easier accessing and evaluating. ESI mass spectra were recorded on a HPLC-MS system (Agilent Technologies 1200) coupled with a 6410 Triple-Quadrupole mass spectrometer, operating in a positive ESI mode. High-resolution mass spectra were recorded on Agilent 6210 Time-of-Flight LC/MS (ESI). UV-Vis spectra were recorded on Cary 100 spectrophotometer and CD spectra were recorded on Jasco J-815 spectropolarimeter in 1.0 cm and 0.1 cm quartz Suprasil cells. Stock solutions of the isolated compounds were prepared for UV-Vis and CD measurements. The measured absorbance A (in UV-Vis) is converted to concentration-independent ε [M−1 cm−1] through the Lambert–Beer equation. The measured ellipticity θ [°] (in CD) is converted into the concentration independent Δε [M−1 cm−1] through the relation Δε = θ/(b × 32 982 × c), where b [cm] is the path length and c [M] is the concentration. NMR spectra were obtained on a Bruker Avance AV300 or AV600 spectrometer, operating at 300 or 600 MHz for 1H and 75 or 150 MHz for 13C; if not indicated further, the spectra were recorded at room temperature. Chemical shifts, δ (ppm), indicate a downfield shift from the internal standard, tetramethylsilane, TMS. Coupling constants, J, are given in Hz. Individual peaks are marked as: singlet (s), doublet (d), triplet (t), quartet (q), quintet (quin.) or multiplet (m). GC-MS data were recorded on Agilent 7890/5977 and Agilent 8860 GC/Agilent 5977 MSD with a SST EI 350 instruments and chiral GC data on Agilent 8890 GC instrument with a FID. |
| Keywords (english) | |
| Language | english |
| DOI | https://doi.org/10.1039/D4DT02519A |
| URN:NBN | urn:nbn:hr:241:591629 |
| Publication | 2025-12-10 |
| Geolocation | Zagreb, Croatia |
| Project | Number: KK.01.1.1.04.0013 Title (croatian): Inovativna rješenja u katalitičkim proizvodnim procesima za potrebe farmaceutske industrije Title (english): Innovative solutions in catalytic processes in the pharmaceutical industry Acronym: CAT PHARMA Leader: Srećko Kirin Jurisdiction: eu Funding stream: European Regional Development Fund |
| Project | Number: IP-2022-10-8456 Title (croatian): Supramolekulska asimetrična kataliza: Prijenos kiralnosti u koordinacijskim kavezima (Cage Cat) Title (english): Supramolecular asymmetric catalysis: Chirality transfer in coordination cages (Cage Cat) Acronym: Cage Cat Leader: Srećko Kirin Jurisdiction: Croatia Funding stream: Research Projects |
| Publisher | Institut Ruđer Bošković Ruđer Bošković Institute |
| Access conditions | Open access |
| Terms of use |  |
| Created on | 2024-12-10 15:43:59 |
