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Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry
Ruđer Bošković Institute, 2025. urn:nbn:hr:241:777970
Jakupec, Nikola; Palčić, Ana

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Dataset: pzc_ir_pxrd_sem_lls_uvvis_sim.zip, 16.46 MB
Access Condition: Access restricted to higher education institution's students and staff in RH
Description:
Set eksperimentalnih podataka (PXRD, IR, SEM, LLS, UV-Vis, simulacije). (Croatian)

Documentation: pseudohalogen-mehanokem-chem_comm-esi-v7.5.docx, 3.09 MB
Access Condition: Access restricted to higher education institution's students and staff in RH
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Electronic supplementary information of the paper detailing experimental methods and procedures (English)

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Jakupec, N. & Palčić, A. (2025). Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry [Data set]. https://urn.nsk.hr/urn:nbn:hr:241:777970.

Jakupec, Nikola and Ana Palčić. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. Institut Ruđer Bošković, 2025. 11 Mar 2025. https://urn.nsk.hr/urn:nbn:hr:241:777970.

Jakupec, Nikola, and Ana Palčić. 2025. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. Institut Ruđer Bošković. https://urn.nsk.hr/urn:nbn:hr:241:777970.

Jakupec, N. and Palčić, A. 2025. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. Institut Ruđer Bošković. [Online]. [Accessed 11 March 2025]. Available from: https://urn.nsk.hr/urn:nbn:hr:241:777970.

Jakupec N, Palčić A. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. [Internet]. Institut Ruđer Bošković; 2025, [cited 2025 March 11] Available from: https://urn.nsk.hr/urn:nbn:hr:241:777970.

N. Jakupec and A. Palčić, Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry, Institut Ruđer Bošković, 2025. Accessed on: Mar 11, 2025. Available: https://urn.nsk.hr/urn:nbn:hr:241:777970.

Title (english)Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry
AuthorNikola Jakupec
Institut Ruđer Bošković
AuthorAna Palčić
Institut Ruđer Bošković
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Inorganic Chemistry
Abstract (english)
In an effort to introduce alternative methods of post-synthetic modification of zeolites, mechanochemistry was utilized for ion-exchange and synthesis of transition metal halide and pseudohalide complexes within FAU-type zeolite cages. Structural characterization of the guest molecules shows a variety of synthetized compounds inside the zeolite cavities.
Methods (english)PXRD patterns of the samples were collected using PANalytical Aeris benchtop powder diffractometer (CuKα radiation with Ni filter; λ= 1.5418 Å, 45 kV, 40 mA) in Bragg-Brentano geometry in a 5°-50° 2θ range (0.025° step). Particle size distribution (PSD) curves were obtained by laser light scattering analysis using Malvern Mastersizer 2000 laser light scattering granulometer. The samples were exposed to ultrasonication during the measurement to prevent agglomeration. Scanning electron microscopy (SEM) images were acquired on a Jeol JSM 7000F scanning electron microscope. Mid-IR spectra were collected on a PerkinElmer Frontier FTIR spectrometer with an attenuated total reflection (ATR) addon in the range of 4000-400 cm-1. Far-IR spectra were collected on a ThermoFisher Nicolet iS50 FTIR spectrometer with an ATR add-on in the range of 800-110 cm-1. Solid-state UV-Vis spectra were obtained by measurement on a Thermo Scientific Evolution 350 UV-Vis spetrometer. Data was visualized in MagicPlot Student and Spectragryph software packages.
Keywords (english)
Languageenglish
URN:NBNurn:nbn:hr:241:777970
Publication2025-03-04
Versionv1.2
ProjectNumber: UIP-2019-04-4977
Title (croatian): Zeoliti s malim šupljinama modificirani bakrom pogodni za primjenu u zaštiti okoliša
Title (english): Copper-modified Small-pore Zeolites Suitable for Environmental Applications
Acronym: SMALLPORE
Leader: Ana Palčić
Jurisdiction: Croatia
Funding stream: Installation Research Projects
PublisherInstitut Ruđer Bošković
Ruđer Bošković Institute
Access conditionsRestricted access
Terms of useLicence In copyright icon
Created on2025-03-04 09:31:17