Skup podataka: pzc_ir_pxrd_sem_lls_uvvis_sim.zip, 16.46 MB Pravo pristupa: Datoteka je dostupna svim korisnicima iz sustava znanosti i visokog obrazovanja RH Opis datoteke: Set eksperimentalnih podataka (PXRD, IR, SEM, LLS, UV-Vis, simulacije). (hrvatski)
Dokumentacija: pseudohalogen-mehanokem-chem_comm-esi-v7.5.docx, 3.09 MB Pravo pristupa: Datoteka je dostupna svim korisnicima iz sustava znanosti i visokog obrazovanja RH Opis datoteke: Electronic supplementary information of the paper detailing experimental methods and procedures (engleski)
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Jakupec, N. i Palčić, A. (2025). Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry [Skup podataka]. https://urn.nsk.hr/urn:nbn:hr:241:777970.
Jakupec, Nikola i Ana Palčić. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. Institut Ruđer Bošković, 2025. 11.03.2025. https://urn.nsk.hr/urn:nbn:hr:241:777970.
Jakupec, Nikola, i Ana Palčić. 2025. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. Institut Ruđer Bošković. https://urn.nsk.hr/urn:nbn:hr:241:777970.
Jakupec, N. i Palčić, A. 2025. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. Institut Ruđer Bošković. [Online]. [Citirano 11.03.2025.]. Preuzeto s: https://urn.nsk.hr/urn:nbn:hr:241:777970.
Jakupec N, Palčić A. Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry. [Internet]. Institut Ruđer Bošković; 2025, [pristupljeno 11.03.2025.] Dostupno na: https://urn.nsk.hr/urn:nbn:hr:241:777970.
N. Jakupec i A. Palčić, Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry, Institut Ruđer Bošković, 2025. Citirano: 11.03.2025. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:241:777970.
In an effort to introduce alternative methods of post-synthetic modification of zeolites, mechanochemistry was utilized for ion-exchange and synthesis of transition metal halide and pseudohalide complexes within FAU-type zeolite cages. Structural characterization of the guest molecules shows a variety of synthetized compounds inside the zeolite cavities.
Metodologija (engleski)
PXRD patterns of the samples were collected using PANalytical Aeris benchtop powder diffractometer (CuKα radiation with Ni filter; λ= 1.5418 Å, 45 kV, 40 mA) in Bragg-Brentano geometry in a 5°-50° 2θ range (0.025° step). Particle size distribution (PSD) curves were obtained by laser light scattering analysis using Malvern Mastersizer 2000 laser light scattering granulometer. The samples were exposed to ultrasonication during the measurement to prevent agglomeration. Scanning electron microscopy (SEM) images were acquired on a Jeol JSM 7000F scanning electron microscope. Mid-IR spectra were collected on a PerkinElmer Frontier FTIR spectrometer with an attenuated total reflection (ATR) addon in the range of 4000-400 cm-1. Far-IR spectra were collected on a ThermoFisher Nicolet iS50 FTIR spectrometer with an ATR add-on in the range of 800-110 cm-1. Solid-state UV-Vis spectra were obtained by measurement on a Thermo Scientific Evolution 350 UV-Vis spetrometer. Data was visualized in MagicPlot Student and Spectragryph software packages.
Šifra: UIP-2019-04-4977 Naziv (hrvatski): Zeoliti s malim šupljinama modificirani bakrom pogodni za primjenu u zaštiti okoliša Naziv (engleski): Copper-modified Small-pore Zeolites Suitable for Environmental Applications Kratica: SMALLPORE Voditelj: Ana Palčić Pravna nadležnost: Hrvatska Financijer: Hrvatska zaklada za znanost Linija financiranja: Installation Research Projects