Dataset: experimentaldata.zip, 141.64 KB Access Condition: Open access Description: Experimental data in nad out of phase: .DSC and .DTA files from Bruker Elexsys EPR spetrometer. Power attenuation was incremented from 26 dB to 56 dB. (English)
Documentation: description.txt, 898 bytes Access Condition: Open access Description: Explanation of what is given in the date set. (English)
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Cite this document
Jurec, J. & Rakvin, B. (2024). Study of Saturation Properties of an Inhomogeneous CW‑EPR Line in the Vicinity of Rabi Resonance [Data set]. https://urn.nsk.hr/urn:nbn:hr:241:090864.
Jurec, Jurica and Boris Rakvin. Study of Saturation Properties of an Inhomogeneous CW‑EPR Line in the Vicinity of Rabi Resonance. Institut Ruđer Bošković, 2024. 18 Nov 2024. https://urn.nsk.hr/urn:nbn:hr:241:090864.
Jurec, Jurica, and Boris Rakvin. 2024. Study of Saturation Properties of an Inhomogeneous CW‑EPR Line in the Vicinity of Rabi Resonance. Institut Ruđer Bošković. https://urn.nsk.hr/urn:nbn:hr:241:090864.
Jurec, J. and Rakvin, B. 2024. Study of Saturation Properties of an Inhomogeneous CW‑EPR Line in the Vicinity of Rabi Resonance. Institut Ruđer Bošković. [Online]. [Accessed 18 November 2024]. Available from: https://urn.nsk.hr/urn:nbn:hr:241:090864.
Jurec J, Rakvin B. Study of Saturation Properties of an Inhomogeneous CW‑EPR Line in the Vicinity of Rabi Resonance. [Internet]. Institut Ruđer Bošković: Grad Zagreb/ Zagreb/ Bijenicka 54, HR; 2024, [cited 2024 November 18] Available from: https://urn.nsk.hr/urn:nbn:hr:241:090864.
J. Jurec and B. Rakvin, Study of Saturation Properties of an Inhomogeneous CW‑EPR Line in the Vicinity of Rabi Resonance, Institut Ruđer Bošković, 2024. Accessed on: Nov 18, 2024. Available: https://urn.nsk.hr/urn:nbn:hr:241:090864.
Scientific / art field, discipline and subdiscipline
NATURAL SCIENCES Physics Condensed Matter Physics
Abstract (english)
We used standard continuous-wave electron paramagnetic resonance (CW-EPR) experiment. We increased magnetic field B1 until reaching Rabi frequency. All spectra were recorded on the room temperature. Spectra were recorded using magnetic field modulation of 100 kHz with modulation amplitude of 27 kHz as the first harmonic for two phase-sensitive detections, detection in-phase with respect to the modulation frequency and detection 90° out-of-phase with respect of the modulation frequency.
Methods (english)
The spectrum of continuous-wave electron paramagnetic resonance (CW-EPR) was analyzed with respect to the shape of the line under microwave (MW) power saturation. The used B1 increases until the Rabi frequency approaches the radiofrequency rf used as the magnetic modulation frequency. Spectra were recorded using magnetic field modulation of 100 kHz with modulation amplitude of 27 kHz as the first harmonic for two phase-sensitive detections, detection in-phase with respect to the modulation frequency and detection 90° out-of-phase with respect of the modulation frequency. For the later detection, the resulting change near Rabi resonance can be related to the expected inversion of modulation sideband lines under resonance conditions. This effect detected in the saturation process on inhomogeneous spectral lines of P1 and E’ centers shows that both samples can be used as a standard for estimation B1 value.
Number: IP-2022-10-9292 Title (croatian): Molekulski magnetizam u naprednim čvrstim i mekim materijalima Title (english): Molecular magnetism in advanced solid and soft materials Acronym: MOMENT Leader: Dijana Žilić Jurisdiction: Croatia Funding stream: Research Projects